Prior to the widespread adoption of LAS as a surfactant
ABS - Branched Alkylbenzene Sulfonate, was commonly used in
detergents. ABS has served consumers well but foam-related
environmental problems began to appear in surface waters,
groundwater, drinking water and in wastewater treatment plants.
These problems were caused by the inability of ABS to biodegrade.
ABS is therefore classified as a non-biodegradable
or a "hard detergent”.
Over the last 25 years ABS has been gradually replaced by
LAS and that has brought great relief to the environment.
Additionally LAS possesses many Processing and Performance
Advantages over ABS, making it the preferred surfactant nowadays.
The following studies from around the world have shown and
proven LAS’s positive impact on the environment. (those
studies are published with kind permission from CLER).
| ..oO( UNITED
STATES )Oo.. |
Surfactant concentrations in river
waters dramatically decreased. The Illinois River at
Peoria, Illinois, is highly polluted because of sewage
and industrial plant effluents and storm water runoff
from the greater Chicago area. From 1959 to 1965, the
average MBAS - Methylene Blue Active Substance concentration
in the river was 0.54 ppm. In the year following the
conversion to LAS, the average MBAS value dropped to
0.22 ppm. By the spring of 1968, it had dropped even
lower, averaging 0.05 ppm. In addition, analytical work
showed that only 20 percent of the MBAS present was
actually LAS.
A recent U.S. monitoring study of 50 river sites directly
below wastewater treatment plants showed that the average
LAS concentration was 0.035 ppm. Furthermore, 90% of
over 500,000 U.S. river miles in the U.S. have less
than .00 4 ppm LAS. |
| ..oO( ENGLAND
)Oo.. |
When ABS was replaced with LAS in
England, the surfactant concentration in river waters
dropped by a factor of five. By 1966, surfactant levels
had reached the lower limits of analytical detection.
Today they are almost certainly lower. These changes
occurred even though the volume of detergents used,
and therefore the amount entering the environment, had
greatly increased. |
| ..oO( GERMANY
)Oo.. |
From 1958 to 1964, MBAS residues
in surface waters of the Rhine River basin increased
constantly, paralleling the rapid increase in ABS consumption.
The conversion to LAS in 1964 resulted in the immediate
reduction of MBAS levels. Average MBAS concentrations
continued to drop until pre-1958 levels were observed
by the late 1970's. This overall reduction occurred
despite a population increase of approximately 6 million
people and a two-fold increase in detergent consumption
over 1958 levels. From 1978 to 1987 the MBAS levels
dropped to below 0.05 ppm. LAS specific analyses suggest
that only about 0.01 ppm LAS is currently present in
the Rhine River. |
| ..oO( JAPAN
)Oo.. |
Similar results were observed in
Japan. One example is that of the Tama River. which
passes through heavily populated areas and receives
large quantities of untreated domestic sewage. Even
though the levels of organ ic pollutants in the river
had reached the 8-10 ppm BOD level by the early 1980's,
the yearly average MBAS residues had steadily decreased
from a high of about 2.5 ppm in 1968 to 0.3 ppm in 1981
as a result of the use of LAS. |
| ..oO( THAILAND
)Oo.. |
In July-August 1983, the average
MBAS residual over the 10-48 kilometer zone of the Chao
Phraya River was 0.34 ppm. After switching to LAS, the
average value over the same zone had decreased by 72
percent to 0.09 5 ppm by July of 1984.
Thus while there is extensive evidence that ABS causes
environmental problems, there is now also overwhelming
evidence that these problems are solved by changing
to the use of LAS. This remains true regardless of geographical
location, climate or environmental conditions. |
|